Spinel (/spɪˈnɛl, ˈspɪnəl/[7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2O
4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals.[5]
| Spinel | |
|---|---|
 Small spinel crystal on top of a white calcite from Mogok, Myanmar, measuring 1.5 × 1.1 × 1 cm in size | |
| General | |
| Category |
|
| Formula (repeating unit) | MgAl 2O 4 |
| IMA symbol | Spl[1] |
| Strunz classification | 4.BB.05 |
| Crystal system | Cubic |
| Crystal class | Hextetrahedral (43m) H–M symbol: (43m)[2][3][4] |
| Space group | F 4 3 m (No. 216) |
| Unit cell | a = 8.0898(9) Å; Z = 8 |
| Identification | |
| Color | Various; red, pink, blue, lavender/violet, dark green, brown, black, colourless |
| Crystal habit | Octahedral or flat triangular plates caused by twinning |
| Twinning | common |
| Cleavage | None |
| Fracture | Conchoidal |
| Mohs scale hardness | 7.5–8.0 |
| Luster | Vitreous |
| Streak | White |
| Diaphaneity | Transparent to opaque |
| Specific gravity | (Depending on the composition) The rare Zn-rich spinel can be as high as 4.40, otherwise it averages from 3.58 to 3.61. |
| Optical properties | Isotropic |
| Refractive index | 1.719 |
| Pleochroism | Absent |
| Solubility | None |
| Other characteristics | Weak to medium magnetic, sometimes fluorescent (red synthetic yes, natural red sometimes) |
| References | [5][6] |
Properties
Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture.[8] Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow.[9] Chromium(III) causes the red color in spinel from Burma.[10] Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels,[11] and the "Côte de Bretagne", formerly from the French Crown jewels.[12] The Samarian Spinel is the largest known spinel in the world, weighing 500 carats (100 g).[13]
The transparent red spinels were called spinel-rubies[14] or balas rubies.[15] In the past, before the arrival of modern science, spinels and rubies were equally known as rubies. After the 18th century, the word ruby was only used for the red gem variety of the mineral corundum, and the word spinel came to be used.[16] "Balas" is derived from Balascia, the ancient name for Badakhshan, a region in central Asia situated in the upper valley of the Panj River, one of the principal tributaries of the Oxus River. However, "Balascia" itself may be derived from Sanskrit bālasūryaka, which translates as "crimson-coloured morning sun".[17] Mines in the Gorno Badakhshan region of Tajikistan constituted for centuries the main source for red and pink spinels.[16]
Occurrence
Geologic occurrence
Spinel is found as a metamorphic mineral in metamorphosed limestones and silica-poor mudstones.[9] It also occurs as a primary mineral in rare mafic igneous rocks; in these igneous rocks, the magmas are relatively deficient in alkalis relative to aluminium, and aluminium oxide may form as the mineral corundum or may combine with magnesia to form spinel. This is why spinel and ruby are often found together. The spinel petrogenesis in mafic magmatic rocks is strongly debated, but certainly results from mafic magma interaction with more evolved magma [18] or rock (e.g. gabbro, troctolite).[19][20]
Spinel, (Mg,Fe)(Al,Cr)2O4, is common in peridotite in the uppermost Earth's mantle, between approximately 20 km to approximately 120 km, possibly to lower depths depending on the chromium content.[21] At significantly shallower depths, above the Moho, calcic plagioclase is the more stable aluminous mineral in peridotite while garnet is the stable phase deeper in the mantle below the spinel stability region.[22]
Spinel, (Mg,Fe)Al2O4, is a common mineral in the Ca-Al-rich inclusions (CAIs) in some chondritic meteorites.[23]
Geographical occurrence
Spinel has long been found in the gemstone-bearing gravel of Sri Lanka and in limestones of the Badakshan Province in modern-day Afghanistan and Tajikistan; and of Mogok in Myanmar. Over the last decades gem quality spinels are found in the marbles of Lục Yên District (Vietnam), Mahenge and Matombo (Tanzania), Tsavo (Kenya) and in the gravels of Tunduru (Tanzania) and Ilakaka (Madagascar).[16][24]
Since 2000, in several locations around the world, spinels have been discovered with unusual vivid pink or blue colors. Such "glowing" spinels are known from Mogok (Myanmar),[25] Mahenge plateau (Tanzania), Lục Yên District (Vietnam)[26] and some more localities. In 2018 bright blue spinels have been reported also in the southern part of Baffin Island (Canada).[27] The pure blue coloration of spinel is caused by small additions of cobalt.[28]
Synthetic spinel
Synthetic spinel can be produced by similar means to synthetic corundum, including the Verneuil method and the flux method pioneered by Edmond Frémy. It is widely used as an inexpensive cut gem in birthstone jewelry for the month of August. Light blue synthetic spinel is a good imitation of aquamarine beryl, and green synthetic spinel is used as an emerald or tourmaline simulant.[29] By 2015, transparent spinel was being made in sheets and other shapes through sintering.[30] Synthetic spinel, which looks like glass but has notably higher strength against pressure, can also have applications in military and commercial use.[31]
See also
Minerals portal- Aluminium oxynitride
- Ceylonite
- The Three Brothers, a lost 14th-century crown jewel with three red spinels in a triangular arrangement
References
Bibliography
External links
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