Allylmagnesium bromide

Chemical compound From Wikipedia, the free encyclopedia

Allylmagnesium bromide is a Grignard reagent used for introducing the allyl group. It is commonly available as a solution in diethyl ether. It may be synthesized by treatment of magnesium with allyl bromide while maintaining the reaction temperature below 0 °C to suppress formation of hexadiene.[1] Allyl chloride can also be used in place of the bromide to give allylmagnesium chloride.[2] These reagents are used to prepare metal allyl complexes.

Quick Facts Names, Identifiers ...
Allylmagnesium bromide
Thumb
Names
IUPAC name
Allylmagnesium bromide
Systematic IUPAC name
Prop-2-enylmagnesium bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.015.497
  • InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1 Y
    Key: FEMBXICCJNZMMC-UHFFFAOYSA-M Y
  • InChI=1/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.BrH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1
    Key: FEMBXICCJNZMMC-NCRCPWRRAY
  • [Br-].[Mg+]CC=C
Properties
C3H5BrMg
Molar mass 145.282 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Close

References

Further reading

Loading related searches...

Wikiwand - on

Seamless Wikipedia browsing. On steroids.