The knockout stages of the Copa Libertadores 2007 tournament were played on a home and away basis. The aggregate score determines the team advancing to the next round, with the away goals rule and a penalty shootout as tiebreakers, in that order. No extra time is played.
Seeding
The teams have been seeded 1 to 8 (first placed teams from group stage) and 9 to 16 (second placed teams from each group) and the ties will be 1 vs 16, 2 vs 15, etc.
| Teams qualified as first place | Teams qualified as second place |
Bracket
| Round of 16 | Quarterfinals | Semifinals | Final | ||||||||||||||||||||||||
| 1 |  Santos
| 2 | 3 | 5 | |||||||||||||||||||||||
| 16 |  Caracas
| 2 | 2 | 4 | |||||||||||||||||||||||
| 1 | Santos
| 0 | 2 | 2 | |||||||||||||||||||||||
| 9 |  América
| 0 | 1 | 1 | |||||||||||||||||||||||
| 8 |  Colo-Colo
| 0 | 2 | 2 | |||||||||||||||||||||||
| 9 | América
| 3 | 1 | 4 | |||||||||||||||||||||||
| 1 | Santos
| 0 | 3 | 3 | |||||||||||||||||||||||
| 7 | Grêmio (*) (a)
| 2 | 1 | 3 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 2 | 2 | |||||||||||||||||||||||
| 10 | São Paulo
| 1 | 0 | 1 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 2 | 2 (4) | |||||||||||||||||||||||
| 15 |  Defensor
| 2 | 0 | 2 (2) | |||||||||||||||||||||||
| 2 | Flamengo
| 0 | 2 | 2 | |||||||||||||||||||||||
| 15 | Defensor
| 3 | 0 | 3 | |||||||||||||||||||||||
| 7 | Grêmio
| 0 | 0 | 0 | |||||||||||||||||||||||
| 11 |  Boca Juniors
| 3 | 2 | 5 | |||||||||||||||||||||||
| 3 |  Libertad
| 2 | 1 | 3 | |||||||||||||||||||||||
| 14 | Paraná Clube
| 1 | 1 | 2 | |||||||||||||||||||||||
| 3 | Libertad
| 1 | 0 | 1 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 1 | 2 | 3 | |||||||||||||||||||||||
| 6 | Vélez Sarsfield
| 0 | 3 | 3 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 3 | 1 | 4 | |||||||||||||||||||||||
| 11 | Boca Juniors
| 1 | 3 | 4 | |||||||||||||||||||||||
| 13 |  Cúcuta Deportivo
| 3 | 0 | 3 | |||||||||||||||||||||||
| 5 | Necaxa
| 2 | 0 | 2 | |||||||||||||||||||||||
| 12 | Nacional
| 3 | 1 | 4 | |||||||||||||||||||||||
| 12 | Nacional
| 0 | 2 | 2 | |||||||||||||||||||||||
| 13 | Cúcuta Deportivo
| 2 | 2 | 4 | |||||||||||||||||||||||
| 4 | Toluca
| 1 | 2 | 3 | |||||||||||||||||||||||
| 13 | Cúcuta Deportivo
| 5 | 0 | 5 | |||||||||||||||||||||||
(*) To prevent a final with two teams from the same country CONMEBOL has paired Santos FC with Grêmio in the Semi-Finals.
Match summaries
Round of 16
First leg
| Caracas FC | 2 – 2 | Santos FC |
|---|---|---|
| Velásquez 55' Vielma 85' |
(Report) | Zé Roberto 15' Kléber 64' |
| São Paulo FC | 1 – 0 | Grêmio |
|---|---|---|
| Miranda 57' | (Report) |
| Boca Juniors | 3 – 0 | Vélez Sársfield |
|---|---|---|
| Riquelme 9' Palermo 61' Rodríguez 89' |
(Report) |
| Cúcuta Deportivo | 5 – 1 | CD Toluca |
|---|---|---|
| Martínez 32', 43', 45' Castro 34' Del Castillo 89' |
(Report) | Sanchéz 1' |
Second leg
| CD Toluca | 2 – 0 | Cúcuta Deportivo |
|---|---|---|
| Zinha 21' Scocco 90' |
(Report) |
| Vélez Sársfield | 3 – 1 | Boca Juniors |
|---|---|---|
| Zárate 14', 36' Ocampo 80' |
(Report) | Bustos (OG) 32' |
| Grêmio | 2 – 0 | São Paulo FC |
|---|---|---|
| Tcheco 17' Diego Souza 74' |
(Report) |
| Santos FC | 3 – 2 | Caracas FC |
|---|---|---|
| Adaílton 34' Zé Roberto 40', 66' |
(Report) | Rey 23' Carpintero 30' |
| Libertad | 1 – 1 | Paraná Clube |
|---|---|---|
| Gamarra 84' | (Report) | Joelson 12' |
Quarterfinals
First leg
| Cúcuta Deportivo | 2 – 0 | Nacional |
|---|---|---|
| Torres 74' Pérez 89' |
(Report) |
| Boca Juniors | 1 – 1 | Libertad |
|---|---|---|
| Palermo 90' | (Report) | Martínez 81' |
Second leg
| Libertad | 0 – 2 | Boca Juniors |
|---|---|---|
| (Report) | Riquelme 61' Palacio 71' |
Semifinals
First leg
| Grêmio | 2 – 0 | Santos FC |
|---|---|---|
| Tcheco 34' Carlos Eduardo 36' |
(Report) |
| Cúcuta Deportivo | 3 – 1 | Boca Juniors |
|---|---|---|
| Pérez 40', 65' Bustos 84' |
(Report) | Ledesma 27' |
Second leg
| Boca Juniors | 3 – 0 | Cúcuta Deportivo |
|---|---|---|
| Riquelme 44' Palermo 60' Battaglia 84' |
(Report) |
Final
First leg
Second leg
| Grêmio | 0 – 2 | Boca Juniors |
|---|---|---|
| (Report) | Riquelme 69', 81' |
Champion
| Copa Libertadores 2007 Winners |
|---|
 Club Atlético Boca Juniors Sixth Title |
References
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