Loading AI tools
From Wikipedia, the free encyclopedia
In chemistry, catalytic resonance theory was developed to describe the kinetics of reaction acceleration using dynamic catalyst surfaces. Catalytic reactions occur on surfaces that undergo variation in surface binding energy and/or entropy, exhibiting overall increase in reaction rate when the surface binding energy frequencies are comparable to the natural frequencies of the surface reaction, adsorption, and desorption.
Catalytic resonance theory is constructed on the Sabatier principle of catalysis developed by French chemistry Paul Sabatier. In the limit of maximum catalytic performance, the surface of a catalyst is neither too strong nor too weak. Strong binding results in an overall catalytic reaction rate limitation due to product desorption, while weak binding catalysts are limited in the rate of surface chemistry. Optimal catalyst performance is depicted as a 'volcano' peak using a descriptor of the chemical reaction defining different catalytic materials. Experimental evidence of the Sabatier principle was first demonstrated by Balandin in 1960.[1][2]
The concept of catalytic resonance was proposed on dynamic interpretation of the Sabatier volcano reaction plot.[3] As described, extension of either side of the volcano plot above the peak defines the timescales of the two rate-limiting phenomena such as surface reaction(s) or desorption.[4] For binding energy oscillation amplitudes that extend across the volcano peak, the amplitude endpoints intersect the transiently accessible faster timescales of independent reaction phenomena. At the conditions of sufficiently fast binding energy oscillation, the transient binding energy variation frequency matches the natural frequencies of the reaction and the rate of overall reaction achieves turnover frequencies greatly in excess of the volcano plot peak.[5] The single resonance frequency (1/s) of the reaction and catalyst at the selected temperature and oscillation amplitude is identified as the purple tie line; all other applied frequencies are either slower or less efficient.
The basis of catalytic resonance theory utilizes the transient behavior of adsorption, surface reactions, and desorption as surface binding energy and surface transition states oscillate with time. The binding energy of a single species, i, is described via a temporal functional including square or sinusoidal waves of frequency, fi, and amplitude, dUi:
Other surface chemical species, j, are related to the oscillating species, i, by the constant linear parameter, gamma γi-j:
The two surface species also share the common enthalpy of adsorption, delta δi-j. Specification of the oscillation frequency and amplitude of species i and relating γi-j and δi-j for all other surface species j permits determination of all chemical surface species adsorption enthalpy with time. The transition state energy of a surface reaction between any two species i and j is predicted by the linear scaling relationship of the Bell–Evans–Polanyi principle which relates to the surface reaction enthalpy, ΔHi-j, to the transition state energy, Ea, by parameters α and β with the following relationship:
The oscillating surface and transition state energies of chemical species alter the kinetic rate constants associated with surface reaction, adsorption, and desorption. The surface reaction rate constant of species i converting to surface species j includes the dynamic activation energy:
The resulting surface chemistry kinetics are then described via a surface reaction rate expression containing dynamic kinetic parameters responding to the oscillation in surface binding energy:
with k reactions with dynamic activation energy. The desorption rate constant also varies with oscillating surface binding energy by:
Implementation of dynamic surface binding energy of a reversible A-to-B reaction on a heterogeneous catalyst in a continuous flow stirred tank reactor operating at 1% conversion of A produces a sinusoidal binding energy in species B as shown.[8] In the transition between surface binding energy amplitude endpoints, the instantaneous reaction rate (i.e., turnover frequency) oscillates over an order of magnitude as a limit cycle solution.
Oscillating binding energies of all surface chemical species introduces periodic instances of transient behavior to the catalytic surface. For slow oscillation frequencies, the transient period is only a small quantity of the oscillation time scale, and the surface reaction achieves a new steady state. However, as the oscillation frequency increases, the surface transient period approaches the timescale of the oscillation and the catalytic surface remains in a constant transient condition. A plot of the averaged turnover frequency of a reaction with respect to applied oscillation frequency identifies the 'resonant' frequency range for which the transient conditions of the catalyst surface match the applied frequencies.[9] The 'resonance band' exists above the Sabatier volcano plot maximum of a static system with average reaction rates as high as five orders of magnitude faster than that achievable by conventional catalysis.
Surface binding energy oscillation also occurs to different extent with the various chemical surface species as defined by the γi-j parameter. For any non-unity γi-j system, the asymmetry in the surface energy profile results in conducting work to bias the reaction to a steady state away from equilibrium.[10] Similar to the controlled directionality of molecular machines, the resulting ratchet (device) energy mechanism selectively moves molecules through a catalytic reaction against a free energy gradient.[11]
Application of dynamic binding energy to a surface with multiple catalytic reactions exhibits complex behavior derived from the differences in the natural frequencies of each chemistry; these frequencies are identified by the inverse of the adsorption, desorption, and surface kinetic rate parameters. Considering a system of two parallel elementary reactions of A-to-B and A-to-C that only occur on a surface, the performance of the catalyst under dynamic conditions will result in varying capability for selecting either reaction product (B or C).[12] For the depicted system, both reactions have the same overall thermodynamics and will produce B and C in equal amounts (50% selectivity) at chemical equilibrium. Under normal static catalyst operation, only product B can be produced at selectivities greater than 50% and product C is never favored. However, as shown, the application of surface binding dynamics in the form of a square wave at varying frequency and fixed oscillation amplitude but varying endpoints exhibits the full range of possible reactant selectivity. In the range of 1-10 Hertz, there exists a small island of parameters for which product C is highly selective; this condition is only accessible via dynamics. [13]
Catalytic reactions on surfaces exhibit an energy ratchet that biases the reaction away from equilibrium.[14] In the simplest form, the catalyst oscillates between two states of stronger or weaker binding, which in this example is referred to as 'green' or 'blue,' respectively. For a single elementary reaction on a catalyst oscillating between two states (green & blue), there exists four rate coefficients in total, one forward (k1) and one reverse (k-1) in each catalyst state. The catalyst switches between catalyst states (j of blue or green) with a frequency, f, with the time in each catalyst state, τj, such that the duty cycle, Dj is defined for catalyst state, j, as the fraction of the time the catalyst exists in state j. For the catalyst in the 'blue' state:
The bias of a catalytic ratchet under dynamic conditions can be predicted via a ratchet directionality metric, λ, that can be calculated from the rate coefficients, ki, and the time constants of the oscillation, τi (or the duty cycle).[15] For a catalyst oscillating between two catalyst states (blue and green), the ratchet directionality metric can be calculated:
For directionality metrics greater than 1, the reaction exhibits forward bias to conversion higher than equilibrium. Directionality metrics less than 1 indicate negative reaction bias to conversion less than equilibrium. For more complicated reactions oscillating between multiple catalyst states, j, the ratchet directionality metric can be calculated based on the rate constants and time scales of all states.
The kinetic bias of an independent catalytic ratchet exists for sufficiently high catalyst oscillation frequencies, f, above the ratchet cutoff frequency, fc, calculated as:
The reaction rate constant, kII, corresponds to the second fastest rate constant in the catalytic elementary step. The duty cycle, DII, corresponds to the duty cycle of the catalyst state, j, with the second fastest reaction rate constant.
For a single independent catalytic elementary step of a reaction on a surface (e.g., A* ↔ B*) at high frequency (f >> fc), the A* surface coverage, θA, can be predicted from the ratchet directionality metric,
Catalytic rate enhancement via dynamic perturbation of surface active sites has been demonstrated experimentally with dynamic electrocatalysis and dynamic photocatalysis. Those results may be explained in the framework of catalytic resonance theory but conclusive evidence is still lacking:
Implementation of catalyst dynamics has been proposed to occur by additional methods using oscillating light, electric potential, and physical perturbation.[29]
Seamless Wikipedia browsing. On steroids.
Every time you click a link to Wikipedia, Wiktionary or Wikiquote in your browser's search results, it will show the modern Wikiwand interface.
Wikiwand extension is a five stars, simple, with minimum permission required to keep your browsing private, safe and transparent.